Maybe your HD is like this:Ubuntu 14.04 on /dev/sda1 Xubuntu 14.04 on /dev/sda5
If you upgraded one of them, some times the GRUB changes of partition. How to fix? Easy, startup from the desire partition and exec:sudo grub-install --root-directory=/boot /dev/sda
update-grub
If you run from a LiveUSB:sudo mount /dev/sda1 /mnt
sudo grub-install --boot-directory=/mnt/boot /dev/sda